Puri, D. M. ; Pande, K. C. ; Mehrotra, R. C. (1962) Derivatives of titanium with compounds having bidentate ligands III. Reactions of titanium alkoxides with acetylacetone Journal of the Less Common Metals, 4 (5). pp. 393-398. ISSN 0022-5088
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/002250...
Related URL: http://dx.doi.org/10.1016/0022-5088(62)90023-1
Abstract
The reactions of titanium alkoxides (methoxide, ethoxide and isopropoxide) with acetylacetone (Hacac) have been found to yield two types of derivatives: Ti(OR)3(acac) and Ti(OR)2(acac)2. Unsuccessful attempts have been made to prepare Ti(OR)(acac)3 by the reaction of Ti(OR)2(acac)2 and Ti(OR)4 with excess of the ligand, which yields a compound with composition TiO(acac)2. The titanyl derivative crystallised from dioxane with a molecule of dioxane of addition. A number of higher alkoxide derivatives with the formulae Ti(OR)3(acac) and Ti(OR)2(acac)2 have been synthesised by alcoholysis reaction of the corresponding methoxide, ethoxide and isopropoxide compounds.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30018 |
| Deposited On: | 23 Dec 2010 03:44 |
| Last Modified: | 08 Jun 2011 05:02 |
Repository Staff Only: item control page
