Triorganotin(IV) O,O-alkylene dithiophosphates

Rao, R. G. ; Srivastava, G. ; Mehrotra, R. C. (1983) Triorganotin(IV) O,O-alkylene dithiophosphates Journal of Organometallic Chemistry, 258 (2). pp. 155-161. ISSN 0022-328X

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The O,O-alkylene dithisphosphates of triorganotin(IV) of the general formula R3SnS2PO2G (where R = C6H5, n-C4H9, n-C3H7, n-C2H5 and CH3; G = CH2C(CH3)2CH2, C(CH3)2C(CH3)2 and C(CH3)2CHCH3 have been synthesized by treatment of triorganotin(IV) chlorides with ammonium O,O-alklene dithiophosphates in 1/1 molar ratio in benzene. These novel complexes are either white crystalline solids or distillable liquids; all are soluble in common organic solvents are are monomeric in refluxing benzene. Like dialkyldithiophosphate derivatives of triorganotin(IV), these cyclic chain derivatives appear to be tetrahedral, the ligands behaving as unidentates.

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