Schiff base complexes of organotin (IV): infrared and mossbauer studies on the addition complexes of N-alkyl(aryl) salicylideneimines

Saraswat, B. S. ; Srivastava, G. ; Mehrotra, R. C. (1979) Schiff base complexes of organotin (IV): infrared and mossbauer studies on the addition complexes of N-alkyl(aryl) salicylideneimines Journal of Organometallic Chemistry, 164 (2). pp. 153-158. ISSN 0022-328X

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...

Related URL: http://dx.doi.org/10.1016/S0022-328X(00)86699-1

Abstract

Fourteen new addition complexes of the type R2SnCl2 · 2 HOC6H4CH=NR' have been synthesized by the reactions of diorganotin dichlorides, R2SnCl2 (where R = Me, Et, n-Bu and Ph), with N-alkyl(aryl)salicylideneimines, HOC6H4CH=NR' (where R' = Me, Et, n-Bu and Ph), in non-aqueous solvents. The complexes are non-electrolytes in nitrobenzene. Infrared and Mossbauer spectroscopic studies indicate an all-trans octahedral geometry for the complexes.

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