Synthesis and reactions of triorganotin dialkyldithiophosphates

Singh, B. P. ; Srivastava, G. ; Mehrotra, R. C. (1979) Synthesis and reactions of triorganotin dialkyldithiophosphates Journal of Organometallic Chemistry, 171 (1). pp. 35-41. ISSN 0022-328X

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...

Related URL: http://dx.doi.org/10.1016/S0022-328X(00)88061-4

Abstract

Triorganotin dialkyldithiophosphates, (RO)2P(=S)SSnR'3 (R = Et, i-Pr, n-Pr or Ph and R' = Me, Et, Bu or Ph), have been synthesised by the interactions of triorganotin hydroxides, oxides and chlorides with dialkyldithiophosphoric acids, (RO)2P(=S)SH, or their (Na, NH4 or lead) salts in anhydrous benzene. An ester-type, structure is proposed, in which the diethyldithiophosphate moiety shows monodentate behaviour.

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