Kumara Swamy, K. C. ; Kommana, Praveen ; Vijjulatha, M. ; Praveen Kumar, K. (2001) Oxidative addition reactions of cyclodiphosph(III)azanes Phosphorus, Sulfur, and Silicon and the Related Elements, 169 (1). pp. 31-34. ISSN 1042-6507
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Official URL: http://www.informaworld.com/smpp/content~db=all~co...
Related URL: http://dx.doi.org/10.1080/10426500108546583
Abstract
The ansa compound {[t-BuN)P]2[O-6-t-Bu-4-Me-C6H2]2CH2} (2) reacts with two mole equivalents of selenium to afford the bis(seleno) compound {[t-BuN)P(Se)]2[O-6-t-Bu-4-Me-C6H2]2CH2} (3); under analogous conditions sulfur gives the P(III)-N-P(V) derivative {[(t-BuN)PN(t-Bu)P(S)][O-6-t-Bu-4-Me-C6H2]2CH2} (4). These reactions are compared with those using [(ArO)PN(t-Bu)]2 (5) and the macrocycle {[t-BuN-P]2(OCH2CMe2CH2O)}2(6).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| Keywords: | Cyclodiphosph(iii)azanes; Oxidative Addition; X-ray Structure |
| ID Code: | 29630 |
| Deposited On: | 23 Dec 2010 05:44 |
| Last Modified: | 07 Jun 2011 06:06 |
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