[n]-Ladderanes: a modular access to norbornyl-fused spacer rods

Mehta, Goverdhan ; Balaji Viswanath, M. ; Kunwar, Ajit C. (1995) [n]-Ladderanes: a modular access to norbornyl-fused spacer rods Synlett, 1995 (4). pp. 317-318. ISSN 0936-5214

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-1995-4965


A cycloaddition cascade between norbornene and 1,2-dicarbomethoxycyclobutadiene provides ready access to norbornyl-fused [n]-ladderanes, which undergo further cycloaddition to 1,3-cyclopentadiene to deliver arrays with norbornyl moieties at both the ends. A short synthesis of norbornyl-fused [8]-ladderane is described.

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