Electrostatic vs. orbital effects as stereoinductive factors in nucleophilic additions to the endo-substituted norbornan-7-one ring system

Mehta, Goverdhan ; Khana, Faiz Ahmed ; Adcock, William (1995) Electrostatic vs. orbital effects as stereoinductive factors in nucleophilic additions to the endo-substituted norbornan-7-one ring system Journal of the Chemical Society, Perkin Transactions 2 (12). pp. 2189-2190. ISSN 0300-9580

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1995...

Related URL: http://dx.doi.org/10.1039/P29950002189

Abstract

Polar-field susceptibility parameters as well as a 13C NMR probe based on the transmission of polar substituent effects in endo-norbornan-7-ones points to the involvement of electrostatic effects in determining π -face selectivities during nucleophilic additions to this ring system.

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