Theoretical and experimental study of [2+2]-photoclosure approachtoward [7]-prismane analogs

Mehta, Goverdhan ; Padma, S. ; Jemmis, Eluvathingal D. ; Leela, G. ; Osawa, Eiji ; Barbiric, Dora A. (1988) Theoretical and experimental study of [2+2]-photoclosure approachtoward [7]-prismane analogs Tetrahedron Letters, 29 (13). pp. 1613-1616. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)80368-8

Abstract

All 39 possible intramolecular [2+2]-photocycloaddition pathways toward [7]-prismane and its homo, seco, homo-seco, bishomo and bishomo-seco analogs have been explored by MM2 .calculations. Fourteen of these are predicted to offer reasonable chance of success. Experimental support for a few of these is provided.

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