Mehta, Goverdhan ; Pan, Subhas Chandra (2004) Total synthesis of the novel, biologically active Epoxyquinone Dimer (±)-torreyanic acid: a Biomimetic approach Organic Letters, 6 (22). pp. 3985-3988. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol0483551
Related URL: http://dx.doi.org/10.1021/ol0483551
Abstract
A total synthesis of the complex, biologically active, dimeric natural product (±)-torreyanic acid, which is composed of seven rings and laced with dense, variegated oxy-functionalization, has been accomplished from readily available allyl-substituted p -benzoquinone 8. Our synthetic stratagem involves crafting an epoxyquinone monomer for use in a biomimetic cascade process involving tandem a 6π electrocyclization and a Diels-Alder dimerization.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 29306 |
| Deposited On: | 17 Dec 2010 08:14 |
| Last Modified: | 01 Mar 2011 11:54 |
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