Farnum, Donald G. ; Mehta, Goverdhan (1969) Proton nuclear magnetic resonance analysis of the stable, classical 2-phenyl-2-norbornyl and related cations Journal of the American Chemical Society, 91 (12). pp. 3256-3261. ISSN 0002-7863
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja01040a028
Related URL: http://dx.doi.org/10.1021/ja01040a028
The 100-Mc NMR spectrum of the 2-phynyl-2-norboronyl cation has been analysed with the aid of deuterium labelling, spin decoupling, and computer simulation. From a comparison with several related norboronyl and bicyclo[2.2.2]octyl system it is concluded that the title cation is classical. Some dramatic examples of the low field chemical shifts of bridgehead norbornyl hydrogen are described.
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