Stereochemistry of nucleophilic additions to 2,3-endo, endo-bridged-7-ketonorbornanes [tricyclo(5.2.1.02,6)decan-10-ones]. Observation of long-range electronic effects

Mehta, Goverdhan ; Praveen, Marapaka (1992) Stereochemistry of nucleophilic additions to 2,3-endo, endo-bridged-7-ketonorbornanes [tricyclo(5.2.1.02,6)decan-10-ones]. Observation of long-range electronic effects Tetrahedron Letters, 33 (13). pp. 1759-1762. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)91726-X

Abstract

The diastereoselectivities exhibited by sterically unbiased endo -tricyclo(5.2.1.02,6)decan-10-ones in nucleophilic additions can be modulated through substituents in the distal five membered ring.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:∏-face Selectivity; Metal-hydride Reduction; Remote Electronic Control
ID Code:29249
Deposited On:17 Dec 2010 08:20
Last Modified:17 Dec 2010 08:20

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