Revelation of pentacyclo (6.2.1.02,7.04,10.05,9) undecane \rightleftharpoons oxa-bird cage equilibrium by 13CMR spectroscopy: fragmentation of caged polycyclic systems with lead tetraacetate

Mehta, Goverdhan ; Singh, Vishwakarma ; Pandey, Paras N. ; Chaudhury, B. ; Duddeck, Helmut (1980) Revelation of pentacyclo (6.2.1.02,7.04,10.05,9) undecane \rightleftharpoons oxa-bird cage equilibrium by 13CMR spectroscopy: fragmentation of caged polycyclic systems with lead tetraacetate Chemistry Letters, 9 (1). pp. 59-62. ISSN 0366-7022

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Official URL: http://www.journalarchive.jst.go.jp/english/jnlabs...

Related URL: http://dx.doi.org/10.1246/cl.1980.59

Abstract

13Cmr evidence is presented to show the existence of pentacyclo (6.2.1.02,7.04,10.05,9) undecane \rightleftharpoons oxa bird cage equilibrium in the parent system 1a. Preparation of some interesting polycyclic compounds via the lead tetracetate fragmentation of polycyclic ketones 1a, 1b and 10 is described.

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