Mehta, Goverdhan ; Srinivasa Reddy, D. (1996) Total synthesis of primnatriene-type sesquiterpenoids of marine origin via regioselective Haller-Bauer cleavage of endo-tricyclo(5.2.1.02,6)decan-10-one system Synlett, 1996 (3). pp. 229-230. ISSN 0936-5214
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-1996-5381
Abstract
Synthesis of densely functionalized aromatic sesquiterpenes 1 and 2a isolated from a marine organism and bearing an Indan framework is reported. The key steps are the regioselective Haller-Bauer cleavage in an appropriately substituted endo-tricyclo(5.2.1.02,6)decan-10-one derivative 4 and further build-up of functionalities on the bicyclic core prior to aromatization.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers Inc. |
| Keywords: | Marine Natural Product; Indane Skeleton; Haller-Bauer Cleavage |
| ID Code: | 29182 |
| Deposited On: | 17 Dec 2010 08:27 |
| Last Modified: | 17 Dec 2010 08:27 |
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