A stereoselective total synthesis of (±)-pentalenene

Mehta, Goverdhan ; Rao, Kasibhatla Srinivas (1985) A stereoselective total synthesis of (±)-pentalenene Journal of the Chemical Society, Chemical Communications (21). pp. 1464-1466. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1985...

Related URL: http://dx.doi.org/10.1039/C39850001464

Abstract

A short, stereoselective synthesis of triquinane sesquiterpene hydrocarbon (±)-pentalenene (4) from commercially available 1,5-dimethylcyclo-octa-1,5-diene (5) involving a transannular cyslisation as the pivotal step is described

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