Mehta, Goverdhan ; Khan, Faiz Ahmed ; Ganguly, Biswajit ; Chandrasekhar, Jayaraman (1994) π-Facial diastereoselection in reductions of sterically unbiased ketones containing the norbornyl framework: further tests for theoretical models Journal of the Chemical Society, Perkin Transactions 2 (11). pp. 2275-2277. ISSN 0300-9580
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1994...
Related URL: http://dx.doi.org/10.1039/P29940002275
Abstract
Ketones 3a-c exhibit syn-face selectivity in borohydride reduction; MNDO and ab initio calculations on model and realistic transition states, respectively, reproduce the preference, but differ on the role of electrostatic and orbital effects.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 29145 |
| Deposited On: | 18 Dec 2010 05:33 |
| Last Modified: | 16 Jul 2012 07:54 |
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