Decahydro-1,3,5-methenocyclopenta[cd]pentalene (trishomocubane) framework: novel photochemical synthesis, acid-catalysed cyclo-reversion, and possible role as a solar energy storage system

Mehta, Goverdhan ; Srikrishna, Adusumilli (1982) Decahydro-1,3,5-methenocyclopenta[cd]pentalene (trishomocubane) framework: novel photochemical synthesis, acid-catalysed cyclo-reversion, and possible role as a solar energy storage system Journal of the Chemical Society, Chemical Communications (4). pp. 218-219. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1982...

Related URL: http://dx.doi.org/10.1039/C39820000218

Abstract

A novel synthetic approach to the decahydro-1,3,5-methenocyclopenta[c,d]pentalene skeleton via intramolecular photocycloaddition of cis,syn,cis-triquinane bis-enones is reported; the facile and efficient acid-induced cycloreversion of these pentacyclic cage compounds to their precursor bis-enones points to the possible role of this systems in the reversible storage of light energy.

Item Type:Article
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ID Code:29139
Deposited On:18 Dec 2010 05:34
Last Modified:04 Jul 2012 09:36

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