Golcondane: a novel, caged, nonacyclic C20H24-hydrocarbon of D2d symmetry

Mehta, Goverdhan ; Reddy, S. Hari Krishna (1993) Golcondane: a novel, caged, nonacyclic C20H24-hydrocarbon of D2d symmetry Angewandte Chemie International Edition, 32 (8). pp. 1160-1161. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.19...

Related URL: http://dx.doi.org/10.1002/anie.199311601

Abstract

In only five steps the title compound 1 can be synthesized from a bisnorbornenobenzoquinone. Intermediates en route to 1 may provide access to other interesting polycycles, for example to cyclic 1,4-tetramers of 1,3-cyclopentadiene such as 3. Golcondane 1 can be considered as a dieter of 2 or a product of a double intramolecular [2 + 2] cycloaddition of 3.

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Deposited On:18 Dec 2010 05:35
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