Viscometric studies of polyvinyl pyridine iodine interaction

Podder, Sunil Kumar ; Basu, Sadhan (1958) Viscometric studies of polyvinyl pyridine iodine interaction Die Makromolekulare Chemie, 28 (1). pp. 72-75. ISSN 0025-116X

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The machanism proposed by Mulliken, on the basis of molecular interaction, for pyridine-iodine interaction in polar medium has been found sufficient to explain the viscosity behaviour of polyvinyl pyridine-iodine systems. Transition from the outer to inner complex has been found to be a time dependent process. Separation of polymer out of a solution containing rather excess iodine has been suggested to be due to intermolecular cross-linking. Direct iodination of the pyridine nucleus has been found to take place after quite a long time.

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ID Code:29106
Deposited On:18 Dec 2010 05:36
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