Free-electron model and triplet-state lifetime of benzene

Sen, Purnendranath ; Basu, Sadhan (1968) Free-electron model and triplet-state lifetime of benzene International Journal of Quantum Chemistry, 2 (2). pp. 183-186. ISSN 0020-7608

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/qua.560...

Related URL: http://dx.doi.org/10.1002/qua.560020202

Abstract

Using the free-electron model the triplet-state lifetime of benzene for the 330 mμ band has been estimated to be about 36 sec, which compares favourably with the corrected experimental value of 30 sec. It has also been established that the perturbing singlet must be a π-σ singlet rather than a π-π singlet.

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Deposited On:18 Dec 2010 05:37
Last Modified:18 Jan 2011 08:45

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