Mehta, Goverdhan ; Nandakumar, Jayakrishnan (2001) Restructuring α -pinene: novel entry into diverse polycarbocyclic frameworks Tetrahedron Letters, 42 (43). pp. 7337-7670. ISSN 0040-4039
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Official URL: http://dx.doi.org/10.1016/S0040-4039(01)01668-9
Related URL: http://dx.doi.org/10.1016/S0040-4039(01)01668-9
Abstract
(-)-α-Pinene 1 has been restructured into a chiral cyclohexenone (+)-6, in which the functionalities were integrated to afford bicyclo[3.3.1]nonan 3,7-diones and a novel tricyclic skeleton 16 related to the sesquiterpene clovene. Intramolecular [2+2] photocycloadditions in (+)-6 and related 5-alkenylcyclohexenones provided an entry into some novel bridged tricyclic systems.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 29090 |
| Deposited On: | 18 Dec 2010 05:37 |
| Last Modified: | 17 May 2016 12:03 |
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