Mehta, Goverdhan ; Bera, Mrinal K. (2004) Towards an enantiospecific total synthesis of garsubellin A and related phloroglucin natural products: the α -pinene approach Tetrahedron Letters, 45 (6). pp. 1113-1116. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2003.12.023
Abstract
The first enantiospecific approach to garsubellin A and related phloroglucin natural product nemorosone, of contemporary interest from (-)-α -pinene, has been delineated. Through a series of stereospecific operations, the requisite stereochemistry of the prenyl groups has been secured. Kende cyclization has been employed as the key step to construct the functionalized bicyclo[3.3.1]nonane core.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 29056 |
| Deposited On: | 18 Dec 2010 05:39 |
| Last Modified: | 17 May 2016 12:02 |
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