Baeyer-Villiger oxidation of norbornan-7-ones: long-range substituent effects on regioselectivity

Mehta, Goverdhan ; Mohal, Narinder (1998) Baeyer-Villiger oxidation of norbornan-7-ones: long-range substituent effects on regioselectivity Journal of the Chemical Society, Perkin Transactions 1 (3). pp. 505-508. ISSN 0300-922X

[img]
Preview
PDF - Publisher Version
80kB

Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1998...

Related URL: http://dx.doi.org/10.1039/A706268K

Abstract

The regioselectivity of the Baeyer-Villiger oxidation of norbornan-7-ones can be steered by the distal 2-endo-substituents present. Hydrolysis of the resulting bicyclic lactones provides a stereospecific route to functionalized cyclohexanes.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:29052
Deposited On:18 Dec 2010 05:39
Last Modified:17 May 2016 12:01

Repository Staff Only: item control page