A new carvone based construction of the ring-A of taxoids

Mehta, Goverdhan ; Chattopadhyay, Shital K. ; Umarye, Jayant D. (1999) A new carvone based construction of the ring-A of taxoids Tetrahedron Letters, 40 (26). pp. 4881-4884. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(99)00902-8

Abstract

A synthesis of the fully functionalized A-ring of taxoids from the commercially available monoterpenic chiron R-carvone is outlined. In this approach, regio- and stereoselective restructuring of alkyl substituents and functionalities is effected on the periphery while retaining the six membered core of carvone.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Taxoids; Barbier Reactions; Allylation
ID Code:28978
Deposited On:18 Dec 2010 05:44
Last Modified:18 Dec 2010 05:44

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