Chromic acid oxidation of bicyclic organoboranes

Bhagwat, M. M. ; Mehrotra, I. ; Devaprabhakara, D. (1974) Chromic acid oxidation of bicyclic organoboranes Journal of Organometallic Chemistry, 82 (3). C27-C29. ISSN 0022-328X

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Bicyclic organoboranes(9-borabicyclo[3.3.1]nonane, 10-borabicyclo[4.3.1]decane and 11-borabicyclo[5.3.1]undecane) on oxidation with an excess of aqueous chromic acid give monocyclic ketones. A mechanism is proposed to account for the formation of this unexpected product.

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