Nagendrappa, G. ; Joshi, G. C. ; Devaprabhakara, D. (1971) π-Complexes of some cyclic allenes with silver(I) and copper(I) Journal of Organometallic Chemistry, 27 (3). pp. 421-426. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...
Related URL: http://dx.doi.org/10.1016/S0022-328X(00)82175-0
Abstract
The cyclic allenes, 1,2,6-cyclononatriene, 1,2,6-cyclodecatriene and 1,2,6,-cyclodecatetraene form well-defined crystalline π-complexes with silver(I) nitrate and copper(I) chloride. The IR spectra of these complexes show two new bands between 1650 and 1900 cm-1 in place of the single allenic band around 1950 cm-1 present in the non-coordinated allenes.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 28358 |
| Deposited On: | 15 Dec 2010 12:10 |
| Last Modified: | 30 May 2011 06:27 |
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