Mehrotra, Indu ; Devaprabhakara, D. (1973) Reactions of disiamyl(3-phenyl-2-butenyl)borane with aldehydes and ketones Journal of Organometallic Chemistry, 51 . pp. 93-98. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...
Related URL: http://dx.doi.org/10.1016/S0022-328X(00)93503-4
Abstract
A substituted allyl organoborane, disiamyl(3-phenyl-2-butenyl)borane has been prepared in situ by the monohydroboration of 3-phenyl-1,2-butadiene with disiamylborane. It reacts readily with butyraldehyde, benzaldehyde, acrolein and acetone to give unsaturated alcohols, possibly via a six-membered transition state involving allylic rearrangement.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 28339 |
| Deposited On: | 15 Dec 2010 12:13 |
| Last Modified: | 30 May 2011 06:23 |
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