Ghatak, Usha R. ; Ray, Jayanta K. ; Chakrabarty, Sephali (1976) Condensed cyclic and bridged-ring systems. Part V. Application of the interamolecular oxo-carbenoid insertion reaction to the preparation of two new bridged-ring ketones Journal of the Chemical Society, Perkin Transactions 1 (18). pp. 1975-1976. ISSN 0300-922X
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1976...
Related URL: http://dx.doi.org/10.1039/P19760001975
Abstract
Two new bridged-ring ketones, 5,6,7,8,10,11-hexahydro-8,12-dimethyl-5,8,11-ethan[1]yl[2]ylidenebenzocyclononen-9-one (5) and 1,3,3a,4,9,9a-hexahydro-1,3a-dimethyl-1,4-ethanocyclopenta[b]naphthalen-2-one (6), have been synthesised by intramolecular oxo-carbenoid C-H insertion reactions in the copper-catalysed decomposition of the 8-diazoacetyl-5,6,7,8,9,10-hexahydro-8,11-dimethyl-5,9-methanobenzocyclo-octenes (3) and (4), epimeric at position 8.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 28144 |
| Deposited On: | 14 Dec 2010 08:14 |
| Last Modified: | 02 Jun 2011 06:58 |
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