An efficient palladium catalyzed stereocontrolled synthesis of 4a-angular methyl substituted hydrofluorenes

Mukhopadhyaya, Jayanta K. ; Pal, Sitaram ; Ghatak, Usha Ranjan (1995) An efficient palladium catalyzed stereocontrolled synthesis of 4a-angular methyl substituted hydrofluorenes Synthetic Communications, 25 (11). pp. 1641-1657. ISSN 0039-7911

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Related URL: http://dx.doi.org/10.1080/00397919508015849

Abstract

A high yield stereoselective synthesis of 4a-angularly methyl substituted cis-hexahydrofluorenes 5a-h and tetrahydrofluorenes 7a,b has been developed by palladium-catalyzed intramolecular Heck-type cyclization of the respective exo-olefins 4a-h and 4a,b through exclusive 5-exo-trig mode.

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