Synthesis of a layered zinc phosphate,[NH₃(CH₂)₂NH₂(CH₂)₃NH₃][Zn₂(PO₄)(HPO₄)₂]·H₂O, and its transformation to a extra-large pore three-dimensional zinc phosphate, [NH₃(CH₂)₂NH₂(CH₂)₃NH₃][Zn₃(PO₄)(HPO₄)₃]

Natarajan, Srinivasan (2002) Synthesis of a layered zinc phosphate,[NH₃(CH₂)₂NH₂(CH₂)₃NH₃][Zn₂(PO₄)(HPO₄)₂]·H₂O, and its transformation to a extra-large pore three-dimensional zinc phosphate, [NH₃(CH₂)₂NH₂(CH₂)₃NH₃][Zn₃(PO₄)(HPO₄)₃] Chemical Communications, 7 . pp. 780-781. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2002...

Related URL: http://dx.doi.org/10.1039/B200293K

Abstract

An unusual two-dimensional zinc phosphate with pendant phosphate groups, projecting into the inter-lamellar space between the layers, has been synthesized and is shown to transform into a three-dimensional structure with 16-membered bifurcated channels, giving evidence for the building up process in the formation of open-framework structures.

Item Type:	Article
Source:	Copyright of this article belongs to Royal Society of Chemistry.
ID Code:	27760
Deposited On:	11 Dec 2010 07:57
Last Modified:	17 May 2016 10:58

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Synthesis of a layered zinc phosphate,[NH3(CH2)2NH2(CH2)3NH3][Zn2(PO4)(HPO4)2]·H2O, and its transformation to a extra-large pore three-dimensional zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn3(PO4)(HPO4)3]

Abstract

Synthesis of a layered zinc phosphate,[NH₃(CH₂)₂NH₂(CH₂)₃NH₃][Zn₂(PO₄)(HPO₄)₂]·H₂O, and its transformation to a extra-large pore three-dimensional zinc phosphate, [NH₃(CH₂)₂NH₂(CH₂)₃NH₃][Zn₃(PO₄)(HPO₄)₃]