Natarajan, Srinivasan ; Attfield, Martin P. ; Cheetham, Anthony K. (1997) Synthesis and characterization of a new zinc phosphate,[NH3(CH2)4NH3]2+[Zn2P3O9(OH)3]2-, containing alternating inorganic-organic layers Journal of Solid State Chemistry, 132 (2). pp. 229-234. ISSN 0022-4596
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00224...
Related URL: http://dx.doi.org/10.1006/jssc.1997.7360
Abstract
A new zinc phosphate [NH3(CH2)4NH3]2+[Zn2P3O9(OH)3]2-was synthesized under acidic conditions at room temperature. It crystallizes in triclinic space group P 1 (No. 2) with lattice parameters a=8.4003(8), b=8.6690(7), c=10.3523(15) Å, α=88.237(1), β=77.732(1), γ=86.406(1)°, V=735.1, Z=2, R=0.33, and Rw=0.041. The structure consists of alternating inorganic and organic layers. The inorganic layers are held together by strong hydrogen bonding, creating cavities in which diprotonated diaminobutane molecules reside.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 27679 |
| Deposited On: | 11 Dec 2010 08:27 |
| Last Modified: | 11 Dec 2010 08:27 |
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