Shibu, Edakkattuparambil S. ; Pradeep, Thalappil (2009) Photoluminescence and temperature dependent emission studies of Au25 clusters in the solid state International Journal of Nanoscience, 8 (1-2). pp. 223-226. ISSN 0219-581X
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Official URL: http://www.worldscinet.com/ijn/08/0801n02/S0219581...
Related URL: http://dx.doi.org/10.1142/S0219581X09005669
Abstract
Effect of ligand exchange on the optical and photoluminescence properties of Au25SG18 (SG-glutathione thiolate) clusters was investigated. A fluorescein-based dye, 5-((2-(and-3)-S-(acetylmercapto)succinoyl)amino)-fluorescein (SAMSA) was anchored on water soluble Au25SG18 clusters by the place exchange reaction and the solid-state emission of the exchange product was studied. Inherent fluorescence image of these clusters was mapped. Organic soluble Au25(SC2H4Ph)18 clusters were synthesized as a model system which also showed temperature-dependent solid-state emission, in good agreement with the results from water soluble Au25 clusters.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to World Scientific Publishing Co Pte Ltd. |
| Keywords: | Au25; Raman Spectroscopy; Solid State Emission; Metal Clusters |
| ID Code: | 27487 |
| Deposited On: | 10 Dec 2010 12:12 |
| Last Modified: | 17 May 2016 10:42 |
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