A priori calculation of the n=1 valence exciton of solid neon

Boursey, E. ; Castex, M. C. ; Chandrasekharan, V. (1977) A priori calculation of the n=1 valence exciton of solid neon Physical Review B, 16 (6). pp. 2858-2862. ISSN 0163-1829

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Official URL: http://prb.aps.org/abstract/PRB/v16/i6/p2858_1

Related URL: http://dx.doi.org/10.1103/PhysRevB.16.2858

Abstract

The energies of the n=1 excitons in solid neon have been calculated on the basis of the ab initio repulsive-potential curves of the molecular excited states derived from 3P and 1P states of neon and the long-range Van der Waals interaction of these states. With this rigorous parameter-free calculation a very good agreement with experimental results is obtained for the first exciton doublet.

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