High temperature ferroic phase transitions and evidence of paraelectric cubic phase in the multiferroic 0.8BiFeO3-0.2BaTiO3

Singh, Anar ; Patel, Jay Prakash ; Pandey, Dhananjai (2009) High temperature ferroic phase transitions and evidence of paraelectric cubic phase in the multiferroic 0.8BiFeO3-0.2BaTiO3 Applied Physics Letters, 95 (14). 142909_1-142909_3. ISSN 0003-6951

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Official URL: http://apl.aip.org/resource/1/applab/v95/i14/p1429...

Related URL: http://dx.doi.org/10.1063/1.3242419

Abstract

We present here results of a powder x-ray diffraction study on the multiferroic 0.8BiFeO3-0.2BaTiO3 in the temperature range of 300-925 K. Our results provide unambiguous evidence for paraelectric cubic phase. We do not find any evidence for intermediate ß-phase in our studies. The rhombohedral to cubic phase transition is shown to be of first order as revealed by the coexistence of cubic and rhombohedral phases over 100 K range and a discontinuous change in the unit cell volume. An anomaly in the unit cell volume at the magnetic transition temperature indicative of the magnetoelastic coupling is also reported.

Item Type:Article
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ID Code:27253
Deposited On:10 Dec 2010 12:53
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