Nature of ferroelectric to paraelectric phase transition in multiferroic 0.8BiFeO3-0.2Pb(Fe1/2Nb1/2)O3 ceramics

Patel, Jay Prakash ; Singh, Anar ; Pandey, Dhananjai (2010) Nature of ferroelectric to paraelectric phase transition in multiferroic 0.8BiFeO3-0.2Pb(Fe1/2Nb1/2)O3 ceramics Journal of Applied Physics, 107 (10). 104115_1-104115_7. ISSN 0021-8979

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Official URL: http://jap.aip.org/resource/1/japiau/v107/i10/p104...

Related URL: http://dx.doi.org/10.1063/1.3428410

Abstract

We present here the results of high temperature powder x-ray diffraction study on 0.8BiFeO3-0.2Pb(Fe1/2Nb1/2)O3, which is isostructural with the well known multiferroic BiFeO3 (BF). It is shown that the room temperature ferroelectric phase of 0.8BF-0.2PFN in the R3c space group transforms to the paraelectric/paraelastic cubic (Pm3m) phase directly without any intermediate "β" phase reported in the literature for pure BF. This transition is of first order type as confirmed by the coexistence of R3c and Pm3m phases over a 100 K range and discontinuous change in the unit cell volume.

Item Type:Article
Source:Copyright of this article belongs to American Institute of Physics.
ID Code:27243
Deposited On:10 Dec 2010 12:54
Last Modified:05 Mar 2011 09:09

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