Banerjee, D. K. ; Bagavant, G. (1960) Isomerisations of substituted β-keto-esters Part II. Isomerisation of ethyl 1-ethoxycarbonyl-2-oxocyclopentylacetate into 2, 3-diethoxycarbonylcyclohexanone Proceedings of the Indian Academy of Sciences, Section A, 52 (4). pp. 165-172. ISSN 0370-0089
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Official URL: http://www.ias.ac.in/j_archive/proca/52/4/165-172/...
Related URL: http://dx.doi.org/10.1007/BF03048968
Abstract
A mechanism for the isomerisation of ethyl 1-ethoxycarbonyl-2-oxocyclopentylacetate (I) into a cyclohexane β-keto-ester as proceeding through an intermediate bicyclic /gb-diketone (VII) has been considered as an alternative mechanism to one earlier suggested. The determination of the structure of the isomerised β-keto-ester as 2, 3-diethoxycarbonylcyclohexanone (V) has provided support for the earlier mechanism.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| ID Code: | 26372 |
| Deposited On: | 06 Dec 2010 12:39 |
| Last Modified: | 17 May 2016 09:40 |
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