Gupta, Rajeev ; Ghosh, Debalina ; Mukherjee, Rabindra Nath (2000) Modelling tyrosinase monooxygenase activity. Activation of dioxygen by dicopper(I) complexes and characterisation of dicopper(II) complexes Proceedings of the Indian Academy of Sciences - Chemical Sciences, 112 (3). pp. 179-186. ISSN 0253-4134
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Official URL: http://ns1.ias.ac.in/chemsci/Pdf-Jnue2K/Pc2920.pdf
Related URL: http://dx.doi.org/10.1007/BF02706170
Abstract
Activation of dioxygen on dicopper(I) centres was systematically investigated using a group of open-chain and a macrocyclicm-xylyl-based dinucleating ligand from a bioinorganic viewpoint. Even though intermediate peroxodicopper(II) species was not detected (even at -80°C for the open-chain system), the putative intermediate reacted with C-H groups in ligands giving oxygenated products (C-OH groups). Absorption, spectroscopic and magnetic properties of the final dicopper(II) complexes have been investigated.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Dioxygen; Dicopper Complexes; M-xylyl-based Dinucleating Ligands; Stoichiometric Oxidation Reactions |
| ID Code: | 26048 |
| Deposited On: | 04 Dec 2010 11:04 |
| Last Modified: | 17 May 2016 09:24 |
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