Aromatic hydroxylation in a new tyrosinase model system and formation of a novel bis(μ-hydroxo)dicopper(II) complex due to an unprecedented ligand coupling reaction

Ghosh, Debalina ; Lal, Tapan K. ; Ghosh, Sangita ; Mukherjee, Rabindra Nath (1996) Aromatic hydroxylation in a new tyrosinase model system and formation of a novel bis(μ-hydroxo)dicopper(II) complex due to an unprecedented ligand coupling reaction Chemical Communications (1). pp. 13-14. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1996...

Related URL: http://dx.doi.org/10.1039/CC9960000013

Abstract

A new binucleating nitrogen-donor ligand exhibits tyrosinase-like activity by bringing about aromatic hydroxylation mediated by copper; the phenoxy- and hydroxyl-bridged copper(II) complex 1 and a novel dihydroxy-bridged copper(II) complex 2 are structurally characterized.

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