IR-laser-induced reaction at catalytic surface: dehydrochlorination of 1,2-dichloroethane at a BaSO4 surface

Naik, P. D. ; Rama Rao, K. V. S. ; Mittal, J. P. (1990) IR-laser-induced reaction at catalytic surface: dehydrochlorination of 1,2-dichloroethane at a BaSO4 surface Chemical Physics Letters, 175 (1-2). pp. 59-66. ISSN 0009-2614

Full text not available from this repository.

Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(90)85518-H

Abstract

Irradiation of BaSO4, in the presence of 1,2-dichloroethane, dissociates 1,2-dichloroethane. Vinylchloride and HCl were formed at low fluence; at high fluence, acetylene was also formed. The decomposition was studied as a function of various parameters. The kinetics deduced and the reaction are attributed to the cooperative vibrational-energy pooling.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:25803
Deposited On:04 Dec 2010 17:08
Last Modified:08 Jun 2011 10:57

Repository Staff Only: item control page