Naik, P. D. ; Rama Rao, K. V. S. ; Mittal, J. P. (1990) IR-laser-induced reaction at catalytic surface: dehydrochlorination of 1,2-dichloroethane at a BaSO4 surface Chemical Physics Letters, 175 (1-2). pp. 59-66. ISSN 0009-2614
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(90)85518-H
Irradiation of BaSO4, in the presence of 1,2-dichloroethane, dissociates 1,2-dichloroethane. Vinylchloride and HCl were formed at low fluence; at high fluence, acetylene was also formed. The decomposition was studied as a function of various parameters. The kinetics deduced and the reaction are attributed to the cooperative vibrational-energy pooling.
|Source:||Copyright of this article belongs to Elsevier Science.|
|Deposited On:||04 Dec 2010 17:08|
|Last Modified:||08 Jun 2011 10:57|
Repository Staff Only: item control page