Naik, P. D. ; Rama Rao, K. V. S. ; Mittal, J. P. (1990) IR-laser-induced reaction at catalytic surface: dehydrochlorination of 1,2-dichloroethane at a BaSO4 surface Chemical Physics Letters, 175 (1-2). pp. 59-66. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(90)85518-H
Abstract
Irradiation of BaSO4, in the presence of 1,2-dichloroethane, dissociates 1,2-dichloroethane. Vinylchloride and HCl were formed at low fluence; at high fluence, acetylene was also formed. The decomposition was studied as a function of various parameters. The kinetics deduced and the reaction are attributed to the cooperative vibrational-energy pooling.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 25803 |
| Deposited On: | 04 Dec 2010 11:38 |
| Last Modified: | 08 Jun 2011 05:27 |
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