UV absorption spectrum and decay kinetics of CF2Br in CO2 laser-induced photodissociation of CF2Br2

Vatsa, R. K. ; Kumar, Awadhesh ; Naik, P. D. ; Rama Rao, K. V. S. ; Mittal, J. P. (1993) UV absorption spectrum and decay kinetics of CF2Br in CO2 laser-induced photodissociation of CF2Br2 Chemical Physics Letters, 207 (1). pp. 75-80. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(93)85014-F

Abstract

A transient absorption spectrum has been observed in the pulsed CO2 laser photodissociation of CF2Br2. This has been assigned to the intermediate CF2Br radical. The spectrum shows a broad band in the region of 220-320 nm with a maximum around 260 nm. The absorption cross section of CF2Br at 262 nm and its dimerization rate constant are reported.

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Deposited On:04 Dec 2010 11:43
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