Parthasarathy, V. ; Sarkar, S. K. ; Pushpa, K. K. ; Rao, K. A. ; Rama Rao, K. V. S. ; Mittal, J. P. (1993) Carbon-13 enrichment by IR laser chemistry of CHF3-Cl2 Applied Physics B: Lasers and Optics, 56 (2). pp. 101-103. ISSN 0946-2171
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Official URL: http://www.springerlink.com/content/p564457l3801u6...
Related URL: http://dx.doi.org/10.1007/BF00325247
Abstract
IR laser chemistry of CHF3 is investigated in both neat form and in the presence of Cl2 for carbon-13 enrichment. Infrared multiple-photon dissociation of CHF3 is an order of magnitude more efficient in the scavenged system compared to the neat case. The photolysis of CHF3/Cl2 mixture results in two products, viz., CF2Cl2 and C2F4Cl2 but with different enrichment factors. The parametric studies show that C2F4Cl2 arises due to MPD of CF2Cl2 in secondary photolysis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer-Verlag. |
| ID Code: | 25744 |
| Deposited On: | 04 Dec 2010 11:46 |
| Last Modified: | 17 May 2016 09:10 |
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