Upadhyaya, Hari P. ; Pavanaja, Ubaradka B. ; Sapre, Avinash V. ; Rama Rao, Kuchimanchi V. S. ; Mittal, Jai P. (1994) Chemiluminescent reaction of oxygen atoms with some nitrile compounds Chemical Physics Letters, 227 (4-5). pp. 511-518. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(94)00861-2
Abstract
In a discharge-flow experiment, chemiluminescent reactions of oxygen atoms (O(3P)) with organic nitriles (RCN) are studied. For unsaturated nitriles RCN (R: CH2=CH; CH2=C(CH3); CH2=CH(CH2)) the observed emission is attributed to CN∗ (B→X) and NO∗ (γ :A→X and β : B→X, bands). For saturated and phenyl nitriles (R: CH3; C2H5; C6H5) emission is only observed from CN∗ (B2∑+). A suitable reaction mechanism for the observed emission is proposed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 25712 |
| Deposited On: | 04 Dec 2010 11:51 |
| Last Modified: | 08 Jun 2011 04:37 |
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