Mohan, Hari ; Maity, D. K. ; Chattopadhyay, S. ; Mittal, J. P. (1999) Transformation of OH-adduct of 1-chloro-4-iodobutane into intra-molecular radical cation in neutral aqueous solution Chemical Physics Letters, 300 (3-4). pp. 493-498. ISSN 0009-2614
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00092...
Related URL: http://dx.doi.org/10.1016/S0009-2614(98)01370-0
Abstract
The iodine centered OH-adduct formed on reaction of •OH radicals with 1-chloro-4-iodobutane in neutral aqueous solution transforms (k=5.4× 105 s-1) to an intra-molecular radical cation(-I∴+Cl-). The unfavorable structural conformation of solute radical cation generated on reaction of OH radicals with 1-chloro-5-iodopentane does not allow the transformation of OH-adduct into an intra-molecular radical and instead a dimer radical cation(-I∴+Cl-) is formed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 25709 |
| Deposited On: | 04 Dec 2010 11:51 |
| Last Modified: | 07 Jun 2011 06:51 |
Repository Staff Only: item control page
