IR and visible luminescence studies in the infrared multiphoton dissociation of 1,2-dibromo-1,1-difluoroethane

Pushpa, K. K. ; Kumar, Awadhesh ; Vatsa, R. K. ; Naik, P. D. ; Rao, K. Annaji ; Mittal, J. P. ; Parthasarathy, V. ; Sarkar, S. K. (1995) IR and visible luminescence studies in the infrared multiphoton dissociation of 1,2-dibromo-1,1-difluoroethane Chemical Physics Letters, 240 (5-6). pp. 489-494. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(95)00569-P

Abstract

The infrared multiphoton dissociation of 1,2-dibromo-1,1-difluoroethane gives rise to IR and visible luminescence. Vibrationally excited parent molecules dissociate via two primary channels yielding bromine and vibrationally excited HBr. The strong visible emission observed between 350 to 750 nm has been assigned to electronically excited carbene CF2Br CH.

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