TEA CO2 laser driven oxidation of tetrafluoroethene and decafluorocyclopentane with molecular oxygen. Evidence for the dioxetane mechanism

Chowdhury, P. K. ; Pola, J. ; Rama Rao, K. V. S. ; Mittal, J. P. (1987) TEA CO2 laser driven oxidation of tetrafluoroethene and decafluorocyclopentane with molecular oxygen. Evidence for the dioxetane mechanism Chemical Physics Letters, 142 (3-4). pp. 252-254. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(87)80932-6

Abstract

Time-resolved emission spectra of the TEA CO2 laser induced oxidation of tetrafiuoroethene and decafluorocyclopentane with molecular oxygen indicate that the oxidation of tetrafluoroethene occurs by at least two processes. The dioxetane mechanism represents a faster reaction compared to the oxidation of transiently formed difluorocarbene.

Item Type:Article
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ID Code:25665
Deposited On:04 Dec 2010 11:58
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