Vatsa, R. K. ; Kumar, Awadhesh ; Naik, P. D. ; Upadhyaya, H. P. ; Pavanaja, U. B. ; Saini, R. D. ; Mittal, J. P. ; Pola, J. (1996) UV spectrum and decay kinetics of transient methylsilene produced in the 193 nm photolysis of gaseous 1-methyl-1-silacyclobutane Chemical Physics Letters, 255 (1-3). pp. 129-133. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(96)00342-9
Abstract
193 nm photolysis of gaseous 1-methyl-1-silacyclobutane with a laser fluence of 50 mJ cm-2 yields a H2C=Si(H)CH3 transient, which decays exclusively by dimerisation to form 1,3-dimethyl-1,3-disilacyclobutane as the stable product with an estimated rate constant of (2.4 ± 0.5) ∗ × 10-11 cm3 molecule-1 s-1.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 25647 |
| Deposited On: | 04 Dec 2010 12:00 |
| Last Modified: | 08 Jun 2011 04:18 |
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