Mossbauer and optical spectra and magnetic susceptibilities of some iron(III)-β-diketone complexes

Mathews, C. K. (1969) Mossbauer and optical spectra and magnetic susceptibilities of some iron(III)-β-diketone complexes Journal of Inorganic and Nuclear Chemistry, 31 (9). pp. 2853-2858. ISSN 0022-1902

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...

Related URL: http://dx.doi.org/10.1016/0022-1902(69)80202-2

Abstract

The Mossbauer and optical spectra, and magnetic susceptibilities of the complexes of iron(III) with thenoyltrifluoroacetone and dibenzoylmethane are reported. The nephelauxetic parameter β35 and the ligand field parameter Δ have been deduced from the optical spectra, and the quadrupole splitting in the Mössbauer spectra is explained in terms of the covalent effects in the metal-oxygen bonding.

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Deposited On:06 Dec 2010 13:27
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