Mathur, Pradeep ; Munkir Hossain, Md. ; Puranik, Vedavati G. ; Tavale, S. S. (1995) Cyclisation of diacetylenes on [Fe2(CO)6(μ-Se2)]: structural characterisation of [(CO)6Fe2{μ-SeCC(H)C(CH3)SeCSe}] Proceedings of the Indian Academy of Sciences - Chemical Sciences, 107 (4). pp. 443-446. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/107/4/443-4...
Related URL: http://dx.doi.org/10.1007/BF02840800
Abstract
Room temperature reactions of [Fe2(CO)6(μ-Se2)] with the diacetylenes, RC= CC= CH(R = Me, n-Bu) yield the products, [(CO)6Fe2{μ-SeCC(H)C(R)SeCSe}]; X-ray analysis of the R = Me compound has been carried out and reveals an unusual cyclisation of the diacetylene with incorporation of a selenium atom to form a cyclic C4Se ligand attached to the Fe2(CO)6Se2 core.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Diacetylene; Cyclisation; Selenophene; Iron Carbonyl |
| ID Code: | 24892 |
| Deposited On: | 01 Dec 2010 12:31 |
| Last Modified: | 17 May 2016 08:28 |
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