Cleavage of carbon-sulfur bonds in thiolato ligands in osmium carbonyl cluster compounds. The synthesis and structural characterization of H₂Os₆(CO)₁₈(.mu.₄-S)(.mu.₃-S) and two isomers of H₂Os₆(CO)₁₇(.mu.₄-S)(.mu.₃-S)

Adams, Richard D. ; Horvath, Istvan T. ; Mathur, Pradeep ; Segmueller, Brigitte E. (1983) Cleavage of carbon-sulfur bonds in thiolato ligands in osmium carbonyl cluster compounds. The synthesis and structural characterization of H₂Os₆(CO)₁₈(.mu.₄-S)(.mu.₃-S) and two isomers of H₂Os₆(CO)₁₇(.mu.₄-S)(.mu.₃-S) Organometallics, 2 (8). pp. 996-1005. ISSN 0276-7333

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Official URL: http://pubs.acs.org/doi/abs/10.1021/om50002a010

Related URL: http://dx.doi.org/10.1021/om50002a010

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Item Type:	Article
Source:	Copyright of this article belongs to American Chemical Society.
ID Code:	24883
Deposited On:	01 Dec 2010 12:32
Last Modified:	03 Mar 2011 09:05

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Cleavage of carbon-sulfur bonds in thiolato ligands in osmium carbonyl cluster compounds. The synthesis and structural characterization of H2Os6(CO)18(.mu.4-S)(.mu.3-S) and two isomers of H2Os6(CO)17(.mu.4-S)(.mu.3-S)

Abstract

Cleavage of carbon-sulfur bonds in thiolato ligands in osmium carbonyl cluster compounds. The synthesis and structural characterization of H₂Os₆(CO)₁₈(.mu.₄-S)(.mu.₃-S) and two isomers of H₂Os₆(CO)₁₇(.mu.₄-S)(.mu.₃-S)