Mathur, Pradeep ; Trivedi, Rajiv ; Satyanarayana, C. V. V. (1996) Selenium-bridged clusters. Synthesis and structural characterization of the μ4-Se twin cluster [(μ-BuSe)Fe2(CO)6]2(μ4-Se) Organometallics, 15 (3). pp. 1062-1064. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/om950705n?prev...
Related URL: http://dx.doi.org/10.1021/om950705n
Abstract
The unusual tetranuclear cluster [(μ-BuSe)Fe2(CO)6]2(μ4-Se) (1) has been obtained from the reaction of a monoanion, derived from Fe2(μ-Se2)(CO)6 and n-BuLi, with 1,3-dibromopropane. Compound 1 has been characterized by IR and 1H, 13C, and 77Se NMR spectroscopy. It has been structurally characterized by single-crystal X-ray diffraction methods. The structure consists of two [(μ-BuSe)Fe2(CO)6] units bridged by a pseudotetrahedral Se atom.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 24844 |
| Deposited On: | 01 Dec 2010 12:40 |
| Last Modified: | 01 Mar 2011 07:21 |
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