Mathur, Pradeep ; Chakrabarty, Debojit ; Munkir Hossain, Md. ; Rashid, Raad S. (1991) Mixed chalcogen carbonyl compounds : IV. Reactivity of Fe2(CO)6(μ-STe) and Fe3(CO)9(μ3-S) (μ3-Te) towards coordinatively unsaturated species Journal of Organometallic Chemistry, 420 (1). pp. 79-86. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002232...
Related URL: http://dx.doi.org/10.1016/0022-328X(91)86447-X
Abstract
Using Fe2(CO)6(μ-STe) and Fe3(CO)9(μ3-S)(μ3-Te) for the addition of coordinatively unsaturated species, the following new mixed metal, mixed chalcogen compounds have been obtained: Fe2(CO)6(μ3-S)(μ3-Te)M(PPh3)2 (M = Pt, Pd), Fe2Ru(CO)9(μ3-S)(μ3-Te) and Fe4-x Rux(CO)11(μ4-S)(μ4-Te) (x = 0-2). The formation of the triphenylphosphine derivatives, Fe3(CO)9-x(PPh3)x(μ3-S)(μ3-Te) (x = 1,2) and Fe3(CO)9(PPh3)(μ3-S)(μ3-Te) are also reported.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 24841 |
| Deposited On: | 01 Dec 2010 12:40 |
| Last Modified: | 01 Dec 2010 12:40 |
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